1、StandardThe Volvo GroupvouvoEstablished February 2003STD 100-0003Versio n 2 Page5 (6)The En glish Ian guage vers ion is the origi nal and the refere nee in case of dispute.英文版為原始版本，當對本文解釋有爭議時以 英文版為準。UNREGESTERED COPY -Possible changes will not be notifiedStandardThe Volvo GroupvouvoEstablished Febru

2、ary 2003STD 100-0003Versio n 2 Page5 (6)UNREGESTERED COPY -Possible changes will not be notifiedStandardThe Volvo GroupvouvoEstablished February 2003STD 100-0003Versio n 2 Page5 (6)Chemical substances whose use within the Volvo 集團內(nèi)部限制使用的化學物質(zhì) Volvo Group shall be limitedVolvo 灰色清單Volvo ' s grey l

3、istUNREGESTERED COPY -Possible changes will not be notifiedStandardThe Volvo GroupvouvoEstablished February 2003STD 100-0003Versio n 2 Page5 (6)UNREGESTERED COPY -Possible changes will not be notifiedStandardThe Volvo GroupvouvoEstablished February 2003STD 100-0003Versio n 2 Page5 (6)s En viro nme責該

4、標準的升級OrientationThis issue differs from issue 1 in that:-a text regardi ng legal requireme nts has bee n added in sect ion 1 Scope and field of applieati on-two new phthalates have bee n added un der Plasticizers in table 1-the limits for metallic lead and lead compounds have bee n added-refere nee

5、to EU directive for ni ckel release has bee n added-the risk of reproductive hazard has bee n added for dibutyl phthalate-in the foot note for hexavale nt chromium, the reference to STD 5732,104 has been replaced by a text stati ng the limit for the free hexavale nt chromium-the substa nces in the t

6、ables have bee n sorted according to English alphabetical order.Two associated sta ndards are STD 1000002“ Chemicalsubsta nce which must not be used withi n the Volvo Group -Volvo ' s black list ” and-ST04100" Substitutes for hazardous chemical substances-Volvo ' s white list ”1 Scope a

7、nd field of applicationAccord ing to a decisi on by the Volvo Group man ageme nt, restrictions have been introduced with respect to the use of certa in chemical substa nces. This sta ndard lists those chemical substa nces, which should not be used in Volvo product ion processes or found in un reacte

8、d form in Volvo ' s products. The Volvo Group Council initiates the updating of the standard.Please note that these lists are only Volvo sta ndards and compliance with these lists does not mean that legal requireme nts concerning hazardous chemical substa nce in differe nt coun tries are fulfill

9、ed.介紹此版本和第一版的不同之處是：在第一節(jié)適用范圍中增加了有關法律要求方面的內(nèi) 容。-在列表增塑劑類中增加了兩種鄰苯二甲酸酯。-在列表金屬類中增加了金屬鉛和鉛的化合物。-根據(jù)歐洲環(huán)境標準的要求增加了對鎳的使用限制。-在鄰苯二甲酸二丁酯的危害項中增加了生殖危害。-在關于六價鉻的腳注中，原來要求參考標準STD5732,104的內(nèi)容被有關自由價鉻限制標準的內(nèi)容所 取代。-列表中的物質(zhì)按英文頭字母順序重新排列了。與此標準有關的兩個標準是 STD 100-0002 “ Volvo集 團內(nèi)部禁止使用的化學物質(zhì)-Volvo黑色清單”和STD 100-0004 “危險化學物質(zhì)的替代品-Volvo白色清 單

10、”。1適用范圍依據(jù)Volvo集團管理層的決定，某些化學物質(zhì)的使用 是受到限制的。此標準列出了在Volvo公司生產(chǎn)過程中不應該使用的化學物質(zhì)，在未處理前，它們也不允 許存在于Volv&的產(chǎn)品中。Volvo集團的環(huán)境委員會負請注意該清單僅僅是Volvo公司的標準，滿足該標準 的要求并不意味就能滿足各國當?shù)赜嘘P危險化學品的 法律限制。UNREGESTERED COPY -Possible changes will not be notifiedStandardThe Volvo GroupvouvoEstablished February 2003STD 100-0003Versio n 2

11、 Page5 (6)Products containing chemical substa nces in cludi ng in this sta ndard shall be kept un der surveilla nce and active work shall be performed to find less hazardous alter natives to be in troduced as soon as this is tech ni cally and econo mically possilbe.含有一種或多種清單列出的化學物質(zhì)的產(chǎn)品必須處于 嚴格的監(jiān)督之下。同時

12、，只要技術和經(jīng)濟條件上一有 可能，就需要采取有效措施尋找危害性更低的替代 品。UNREGESTERED COPY -Possible changes will not be notifiedStandardThe Volvo GroupvouvoEstablished February 2003STD 100-0003Versio n 2 Page5 (6)Befor new products co ntai ning one or more of the在含有清單中所列的一種或幾種化學物質(zhì)的新產(chǎn)品投chemical substances listed in this standard put

13、ting into use, 入使用之前，必須做一個評審以保證盡可能少的使用 an assessme nt shall always be made regarding the possible 有危害的物質(zhì)。use of less hazardous products.The restrict ion refer to each deliberate use of the chemical substa nces specified in the sta ndard at concen trati ons exceedi ng 0.1 per cent by mass. Specific l

14、imits no ted in the list apply to some substances. However, the restriction does not apply in those cases a chemical substa nee occurs in the form of impurities in a specific product, that is, nondesired occurre nee in very low concen trati ons, or whe n it is han dled in small qua ntities by traine

15、d staff at laboratories.列表給出了每一種化學物質(zhì)限制使用的具體場合，在 大批量的生產(chǎn)過程中，灰色清單上的化學物質(zhì)濃度不 允許超過0.1%。其中一些物質(zhì)注明了特殊的限制。然 而，特殊產(chǎn)品中低濃度非希望的化學生成雜質(zhì)并不包 括在清單禁止之列；在試驗室中由專業(yè)人員控制的少 量化學品也不在清單禁止之列。Excepti ons may also be made for chemical substa nces used in processes con trolled by legal requireme nts or safety regulations where it is

16、 not possible for Volvo exclusively to limit the use of the substance in question. In situati ons where excepti ons have to be made, special precauti onary measures shall be take n to preve nt in jurious effects on huma n or the en vir onment. The respective Volvo compa ny shall decide upon any exce

17、pti ons.Refere nce to this sta ndard can be made in desig n prerequisites (DPR) and is made inequiremen'tRorsuppliers and con tractors -En vir onment ” . For an examj在Volvo公司沒有必要單獨禁止有爭議的化學物質(zhì)使 用的情況下，如過程控制符合法律要求和安全規(guī)章， 清單物質(zhì)的限制使用允許有例外，前提是采取特別的 預防措施防止對人或環(huán)境產(chǎn)生危害。 Volvo各公司可以 自己決定是否援引例外條例。在有關設計前提條件(DPR)的

18、標準和文件“對供應商和 承包方的要求-環(huán)境部分”中可能要求參考本標準。在 第三節(jié)演示了一個在文件中要求參考本標準的例子。of refere nce to this sta ndard, see sect ion 3 Refere nce indocume ntati on.2 List of substances物 質(zhì)清單Table 1EGroup 分組Substa nee n ame化學物質(zhì)名CAS noKEMI listed 10)Example of type or area of use典型使用場合Risk 2) 危害Acids 酸類Hydrofluoric acid 氫氟酸7664-

19、39-3OPickli ng, etchi ng 酸洗，蝕刻TAdditives添加劑Diphe ny lam ine 3) 二苯胺122-39-4OLubrica nts潤滑劑E, TSodium nitrite 亞硝酸鈉7632-00-0An ti-rust age nt 防銹劑C, TBiocides (No concen trati on limits) 生物殺火劑Chlorocresol(meta-) 對氯代間甲酚59-50-7OLubrica nts, paints 潤滑劑，油漆E, AChlorocresol(ortho-)4-氯-2-甲基苯酚1570-64-5Lubrica n

20、ts, paints 潤滑劑，油漆E(probably)Chloromethyl isothiazoli none5-氯-2-甲基-異噻唑啉-3-酮 Methyl isothiazoli none2-甲基-4-異噻唑啉-3-酮Kath on CG凱松(為上兩種物質(zhì)的混合物)26172-55-42682-20-455965-84-9OOOAqueous soluti on 工業(yè)循環(huán)水處理劑AOrganotin Comp. (trialkyl) 三烷基錫類化合物SeveralO, RCooli ng water冷卻水EThiram (TMTD) 雙硫胺甲酰137-26-8OA, EComplex

21、mixtures 復雜混合物Coal tar煤焦油8007-45-265996-91-0O, RDistillation product, filler 蒸餾產(chǎn)品，填充物C, EColoph ony (ros in) (Applies to>1%) 松香(應用超過1%)8050-09-78052-1-0673138-82-6OOOAdhesives, pain ts, cutt ing fluids粘合劑，涂料，切削液ACreosote木榴油8001-58-9O, RDistillation product, filler 蒸餾產(chǎn)品，填充物C, EFlame retarda nts阻燃劑

22、Bromi nated (not PBB + PBDE) 溴化物(不包括PBB和PBDE)SeveralOTextiles, plastics 織物，塑料E(probably)有可能Triphe nyl phosphate 磷酸三苯脂115-86-6RAlso as an tioxida nt也用作抗氧化劑EHarde ners 硬化劑2,4-Tolue ne diisocya nate甲苯-2,4二異氰酸酯584-84-9OPUR foams, adhesivesPUR發(fā)泡劑，粘合劑A(asthma) 哮喘2,6-Tolue ne diisocya nate甲苯-2,6二異氰酸酯91-08-

23、7OPUR foams, adhesivesPUR發(fā)泡劑，粘合劑A(asthma)哮喘TGIC吠嗶克（異氰脲酸三縮水甘 油酯）2451-62-9OPowder paints 粉末涂料T(mutage n)誘變劑Group 分組Substa nee n ame化學物質(zhì)名CAS noKEMI listed 10)Example of type or area of use典型使用場合Risk 2) 危害HCFC compou nds4)氫氯氟烴類化合 物HCFC 141b 二氯氟乙烷1717-00-6OCooli ng age nt 冷媒OHCFC 142b一氯二氟乙烷75-68-3OCooli

24、ng age nt 冷媒OHCFC 22 二氟氯甲烷75-45-6OCooli ng age nt 冷媒OMetals金屬Arse nic + eompo unds 砷及砷的化合物SeveralO, Rwood preservative 木材防腐N, C, ECadmium in batteries 5) 電池中的鎘SeveralO, RAccumulators 蓄電池C, EChromium (6+) eompo und 6) 六價鉻化合物SeveralO, RSurface treatme nt 表面處理A, C, ELead alloys 7)鉛合金SeveralO, RAlloy 合金

25、N, ELead + eompo und 8) 鉛及其化合物SeveralO, RPigment in paints涂料中的顏料N, ENickle 9) 鎳7440-02-0O, RSurface treatme nt 表面處理AStron tium chromate 鉻酸鍶7789-06-2O, RPin gme nt 顏料CZinc chromate鉻酸鋅13530-65-9-Pin gme nt 顏料CPlasticizers 增塑劑Butyl ben zyl phthalate 鄰苯二甲酸丁芐酯85-68-7-Adhesives, paints粘合劑，涂料EDibutyl phtha

26、late 鄰苯二甲酸二丁酯84-74-2OAdhesives, paints 粘合劑，涂料E, RDi (2-ethylhexyl)phthalate DEHP鄰苯二甲酸二-(2-乙基已 基)酯117-81-7RSeala nts, plastics 密封劑，塑料RDi(methoxyethyl)phthalate 鄰苯二甲酸二-(2-甲基乙 基)酯117-82-8Radhesives, plastics 粘合劑，塑料RDimethyl phthalate 鄰苯二甲酸二甲酯131-11-3-Harde ners, paintsTSolve nts 溶劑Chloroform 氯仿67-66-3R

27、Solve nt溶劑C, R1.2- Dichloroetha ne1.2- 二氯乙烷107-06-2O, RAdditive for fuels 燃油添加劑Cn-Hexa ne正已烷110-54-3-Solve nt溶劑NLim onene (Applies to> 1%) 檸檬油精(應用超過1%)138-86-35989-27-5OSolve nt溶劑A, EGroup 分組Substa nce n ame化學物質(zhì)名CAS no. 17KEMI listed 10)Example of type or area of use典型使用場合Risk 2) 危害2-Methoxy-1-pr

28、opa nol (Applies to > 0.5%) 2-甲基丙醇(應用超過 0.5%)1589-47-5Solve nt溶劑RTrichloroethyle ne 三氯乙烯79-01-6-Solve nt溶劑CSurface-active age nts 表面活性劑DHTDMAC61789-80-8OSofte ner柔軟劑EDSDMAC雙十八烷基二甲基氯化銨107-64-2O, RRinsing age nt水處理凝絮劑EDTDMAC68783-78-8OVehicle care products 車用保養(yǎng)產(chǎn)品1) CAS no.=Chemical Abstract Service

29、 registry nu mber. Intern ati on ally applied scie ntific in dex ide ntify ing chemical substa nces.CAS no.=化學制品摘要服務登錄碼，簡稱CAS登錄碼，為國際通用的用來認定化學物質(zhì)的科學編碼。2) A = Allergy, C = Cancer, T = Toxic, E = Environmentally hazardous, N = Neurotoxic, O = Ozone depletion, R = Reproductive hazards.A =過敏，C =癌癥，T =有毒，E

30、 =危害環(huán)境，N =毒害神經(jīng)，O =損耗臭氧層，R=危害生物生殖功能3) Nitrite can form carcinogenic nitrosamines if amines are present.亞硝酸鹽如果和胺類物質(zhì)接觸有可能形成致癌的亞硝酸胺。4) HCFC used as blowi ng age nt in foam plastics (PUR) or as solve nt is covered by the black list, STD 100-0002. HCFC used as cooli ng age nt is covered by the grey list,

31、STD 100-0003.當HCFC用作泡沫塑料的發(fā)泡劑或溶劑時，它被黑色清單覆蓋。當HCFC用作冷卻介質(zhì)時，它被灰色清單覆蓋。5) The use of cadmium in batteries is covered by the grey list, STD 100-0003, and other application by the black list,STD 100-0002,當鎘用在電池中時，它被灰色清單覆蓋；鎘的其他應用被黑色清單覆蓋。6) For each in dividual batch of surface treated parts, the mea n value o

32、f free hexavale nt chromium must not exceed20.3 ©/cm when tested in accordanee with STD 5713,102.用Volvo標準STD 5713,102的方法測試，對每一批表面處理的零件，自由六價鉻含量的平均值不得超過20.3 g/cm。7) Concentration limits in accordance with the EU ELV directive are, for example, for steel 0.35%, for aluminum 0.4% and for copper 0.4%.鉛在合金中含量限制值與歐盟的ELV (End-of-life Vehicles)指導一致。例如，在鋼中為0.35%，在鋁合金中為0.4%，在銅合金中為 copper 0.4%。8) The grey list ' srgelireit of 0.1 per cent by mass applies to metallic lead if the component is not exempted in Annex 2 of the EU ELV directive. A l